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A mea culpa: Turns out that the chemical reaction requires a lot of hydrogen, requiring the water-gas shift (WGS), which generates a lot of CO₂. That means the OX-ZEO process emits as much CO₂ as the methanol route for coal-to-olefins:

CO + H₂O → CO₂ + H₂

2CO + 4H₂ → C₂H₄ + 2H₂O

1 mol C₂H₄ : 4 mol H₂ : 4 mol CO₂

28 g/mol × 1 mol C₂H₄ : 44 g/mol × 4 mol CO₂

28 g C₂H₄ : 176 g CO₂

1 g C₂H₄ : 176/28 g CO₂

1 g C₂H₄ : ~6.29 g CO₂

Standard methanol route process emissions:

CO + H₂O → CO₂ + H₂

CO + 2H₂ → CH₃OH

2CH₃OH → C₂H₄

1 mol C₂H₄ : 2 mol CH₃OH : 4 mol H₂ : 4 mol CO₂

28 g C₂H₄ : 176 g CO₂

1 g C₂H₄ : 176/28 g CO₂

1 g C₂H₄ : ~6.29 g CO₂

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