Discussion about this post

User's avatar
Mark's avatar
Jun 28Edited

A mea culpa: Turns out that the chemical reaction requires a lot of hydrogen, requiring the water-gas shift (WGS), which generates a lot of CO₂. That means the OX-ZEO process emits as much CO₂ as the methanol route for coal-to-olefins:

CO + H₂O → CO₂ + H₂

2CO + 4H₂ → C₂H₄ + 2H₂O

1 mol C₂H₄ : 4 mol H₂ : 4 mol CO₂

28 g/mol × 1 mol C₂H₄ : 44 g/mol × 4 mol CO₂

28 g C₂H₄ : 176 g CO₂

1 g C₂H₄ : 176/28 g CO₂

1 g C₂H₄ : ~6.29 g CO₂

Standard methanol route process emissions:

CO + H₂O → CO₂ + H₂

CO + 2H₂ → CH₃OH

2CH₃OH → C₂H₄

1 mol C₂H₄ : 2 mol CH₃OH : 4 mol H₂ : 4 mol CO₂

28 g C₂H₄ : 176 g CO₂

1 g C₂H₄ : 176/28 g CO₂

1 g C₂H₄ : ~6.29 g CO₂

Nitin Pandit's avatar

I am not sure if I agree with the entire chain of logic here, but given that the focus is on the role of biomass in the fuel system, and that too, to largely meet urban requirements, the conclusions appear pleasing on the surface... even though the approach of a supply driven system feels quite distorting.

As such, it is more useful to look at biomass for storage, high value material uses and distributed end use driven energy use (ref: "Banking with Biomass by K. R. Datye) in the developing world.

No posts

Ready for more?